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Influence of pore structure on biologically activated carbon performance and biofilm microbial characteristics

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1419-1

摘要：

• Pore structure affects biologically activated carbon performance.

关键词： Granular activated carbon     Biologically activated carbon filter     Bacterial community structure     Pore structure    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO

Zeinab JAMALZADEH, Mohammad HAGHIGHI, Nazli ASGARI

《环境科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 365-381 doi: 10.1007/s11783-013-0520-5

摘要： In this work, xylene removal from waste gas streams was investigated via catalytic oxidation over Pd/carbon-zeolite and Pd/carbon-CeO nanocatalysts. Activated carbon was obtained from pine cone chemically activated using ZnCl and modified by H PO . Natural zeolite of clinoptilolite was modified by acid treatment with HCl, while nano-ceria was synthesized via redox method. Mixed supports of carbon-zeolite and carbon-ceria were prepared and palladium was dispersed over them via impregnation method. The prepared samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Brunauer-Emmett-Teller surface area (BET), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric (TG) techniques. Characterization of nanocatalysts revealed a good morphology with an average particle size in a nano range, and confirmed the formation of nano-ceria with an average crystallite size below 60 nm. BET analysis indicated a considerable surface area for catalysts (~1000 m ·g ). FTIR patterns demonstrated that the surface groups of synthesized catalysts are in good agreement with the patterns of materials applied in catalyst synthesis. The performance of catalysts was assessed in a low-pressure catalytic oxidation pilot in the temperature range of 100°C–250°C. According to the reaction data, the synthesized catalysts have been shown to be so advantageous in the removal of volatile organic compounds (VOCs), representing high catalytic performance of 98% for the abatement of xylene at 250°C. Furthermore, a reaction network is proposed for catalytic oxidation of xylene over nanocatalysts.

关键词： Pd/carbon-CeO2     Pd/carbon-zeolite     pine cone     ZnCl2     catalytic oxidation     xylene    

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Tripotassium citrate monohydrate derived carbon nanosheets as a competent assistant to manganese dioxidewith remarkable performance in the supercapacitor

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 420-432 doi: 10.1007/s11705-021-2065-7

摘要： Production cost, capacitance, and electrode materials safety are the key factors to be concerned about for supercapacitors. In this work, a type of carbon nanosheets was produced through the carbonization of tripotassium citrate monohydrate and nitric acidification. Subsequently, a well-designed manganese dioxide/carbon nanosheets composite was synthesized through hydrothermal treating. The carbon nanosheets served as the substrate for growing the manganese dioxide, regulating its distribution, and preventing it from inhomogeneous dimensions and severe agglomeration. Many manganese dioxide nanosheets grew vertically on the numerous functional groups generated on the surface of the carbon nanosheets during acidification. The synergistic combination of carbon nanosheets and manganese dioxide tailors the electrochemical performance of the composite, which benefits from the excellent conductivity and stability of carbon nanosheets. The carbon nanosheets derived from tripotassium citrate monohydrate are conducive to the remarkable performance of manganese dioxide/carbon nanosheets electrode. Finally, an asymmetric supercapacitor with active carbon as the cathode and manganese dioxide/carbon nanosheets as the anode was assembled, achieving an outstanding energy density of 54.68 Wh·kg–1 and remarkable power density of 6399.2 W·kg–1 superior to conventional lead-acid batteries. After 10000 charge-discharge cycles, the device retained 75.3% of the initial capacitance, showing good cycle stability. Two assembled asymmetric supercapacitors in series charged for 3 min could power a yellow light emitting diode with an operating voltage of 2 V for 2 min. This study may provide valuable insights for applying carbon materials and manganese dioxide in the energy storage field.

关键词： carbon nanosheets     manganese dioxide     asymmetric supercapacitors     energy density     power density    

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Insights into carbon-based materials for catalytic dehydrogenation of low-carbon alkanes and ethylbenzene

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1623-1648 doi: 10.1007/s11705-023-2328-6

摘要： Direct dehydrogenation with high selectivity and oxidative dehydrogenation with low thermal limit has been regarded as promising methods to solve the increasing demands of light olefins and styrene. Metal-based catalysts have shown remarkable performance for these reactions, such as Pt, CrOx, Co, ZrOx, Zn and V. Compared with metal-based catalysts, carbon materials with stable structure, rich pore texture and large surface area, are ideal platforms as the catalysts and the supports for dehydrogenation reactions. In this review, carbon materials applied in direct dehydrogenation and oxidative dehydrogenation reactions including ordered mesoporous carbon, carbon nanodiamond, carbon nanotubes, graphene and activated carbon, are summarized. A general introduction to the dehydrogenation mechanism and active sites of carbon catalysts is briefly presented to provide a deep understanding of the carbon-based materials used in dehydrogenation reactions. The unique structure of each carbon material is presented, and the diversified synthesis methods of carbon catalysts are clarified. The approaches for promoting the catalytic activity of carbon catalysts are elaborated with respect to preparation method optimization, suitable structure design and heteroatom doping. The regeneration mechanism of carbon-based catalysts is discussed for providing guidance on catalytic performance enhancement. In addition, carbon materials as the support of metal-based catalysts contribute to exploiting the excellent catalytic performance of catalysts due to superior structural characteristics. In the end, the challenges in current research and strategies for future improvements are proposed.

关键词： carbon materials     dehydrogenation     active sites     mechanism     catalytic performance     support    

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Construction of NiCoO nanoflake arrays on cellulose-derived carbon nanofibers as a freestanding electrodefor high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 691-703 doi: 10.1007/s11705-022-2268-6

摘要： Cellulose has a wide range of applications in many fields due to their naturally degradable and low-cost characteristics, but few studies can achieve cellulose-nanofibers by conventional electrospinning. Herein, we demonstrate that the freestanding cellulose-based carbon nanofibers are successfully obtained by a special design of electrospinning firstly, pre-oxidation and high-temperature carbonization (1600 °C), which display a superior electrical conductivity of 31.2 S·cm–1 and larger specific surface area of 35.61 m2·g–1 than that of the polyacrylonitrile-based carbon nanofibers (electrical conductivity of 18.5 S·cm–1, specific surface area of 12 m2·g–1). The NiCo2O4 nanoflake arrays are grown uniformly on the cellulose-based carbon nanofibers successfully by a facile one-step solvothermal and calcination method. The as-prepared cellulose-based carbon nanofibers/NiCo2O4 nanoflake arrays are directly used as electrodes to achieve a high specific capacitance of 1010 F·g–1 at 1 A·g–1 and a good cycling stability with 90.84% capacitance retention after 3000 times at 10 A·g–1. Furthermore, the all-solid-state symmetric supercapacitors assembled from the cellulose-based carbon nanofibers/NiCo2O4 deliver a high energy density of 62 W·h·kg–1 at a power density of 1200 W·kg–1. Six all-solid-state symmetric supercapacitors in series can also power a ‘DHU’ logo consisted of 36 light emitting diodes, confirming that the cellulose-based carbon nanofiber is a promising carbon matrix material for energy storage devices.

关键词： cellulose     carbon nanofibers     NiCo2O4     supercapacitors    

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“Charging” the cigarette butt: heteroatomic porous carbon nanosheets with edge-induced topological defectsfor enhanced oxygen evolution performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1755-1764 doi: 10.1007/s11705-023-2318-8

摘要： Owing to the complexity of electron transfer pathways, the sluggish oxygen evolution reaction process is defined as the bottleneck for the practical application of Zn–air batteries. In this effort, metal nanoparticles (Co, Ni, Fe, etc.) encapsulated within nitrogen-doped carbon materials with abundant edge sites were synthesized by one-step pyrolysis treatment using cigarette butts as raw materials, which can drastically accelerate the overall rate of oxygen evolution reaction by facilitating the adsorption of oxygenated intermediates by the edge-induced topological defects. The prepared catalyst of nitrogen-doped carbon porous nanosheets loaded with Co nanoparticles (Co@NC-500) exhibits enhanced catalytic activity toward oxygen evolution reaction, with a low overpotential of 350 mV at the current density of 10 mA·cm–2. Furthermore, the Zn–air battery assembled with Co@NC-500 catalyst demonstrates a desirable performance affording an open-circuit potential of 1.336 V and power density of 33.6 mW·cm–2, indicating considerable practical application potential.

关键词： oxygen evolution reaction     porous carbon nanosheets     Co nanoparticles     edge-induced topological defects     Zn–air batteries    

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Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodesfor high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 504-515 doi: 10.1007/s11705-022-2260-1

摘要： Phenolic resins were employed to prepare electrospun porous carbon nanofibers with a high specific surface area as free-standing electrodes for high-performance supercapacitors. However, the sustainable development of conventional phenolic resin has been challenged by petroleum-based phenol and formaldehyde. Lignin with abundant phenolic hydroxyl groups is the main non-petroleum resource that can provide renewable aromatic compounds. Hence, lignin, phenol, and furfural were used to synthesize bio-based phenolic resins, and the activated carbon nanofibers were obtained by electrospinning and one-step carbonization activation. Fourier transform infrared and differential scanning calorimetry were used to characterize the structural and thermal properties. The results reveal that the apparent activation energy of the curing reaction is 89.21 kJ·mol–1 and the reaction order is 0.78. The activated carbon nanofibers show a uniform diameter, specific surface area up to 1100 m2·g–1, and total pore volume of 0.62 cm3·g–1. The electrode demonstrates a specific capacitance of 238 F·g–1 (0.1 A·g–1) and good rate capability. The symmetric supercapacitor yields a high energy density of 26.39 W·h·kg–1 at 100 W·kg–1 and an excellent capacitance retention of 98% after 10000 cycles. These results confirm that the activated carbon nanofiber from bio-based phenolic resins can be applied as electrode material for high-performance supercapacitors.

关键词： lignin     bio-based phenolic resins     electrospinning     activated carbon nanofibers     supercapacitors    

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Recovery and reuse of floc sludge for high-performance capacitors

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1512-5

摘要：

• The feasibility of facile fabrication of capacitor from floc sludge is discussed.

关键词： Floc sludge     Porous carbon electrode     Energy storage performance     Supercapacitors    

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The preparation and performance of lignin-based activated carbon fiber adsorbents for treating gaseous

Min Song, Wei Zhang, Yongsheng Chen, Jinming Luo, John C. Crittenden

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 328-337 doi: 10.1007/s11705-017-1646-y

摘要： Two types of lignin-based carbon fibers were prepared by electrospinning method. The first was activated with Fe O (LCF-Fe), and the second was not activated with Fe O (LCF). Gas phase adsorption isotherms for toluene on LCF-Fe and LCF were studied. The gas phase adsorption isotherm for 0% RH showed LCF-Fe have about 439 mg/g adsorption capacity which was close to that of commercially available activated carbon (500 mg/g). The Dubinin-Radushkevich equation described the isotherm data very well. Competitive adsorption isotherms between water vapor and toluene were measured for their RH from 0 to 80%. The effect of humidity on toluene gas-phase adsorption was predicted by using the Okazaki et al. model. In addition, a constant pattern homogeneous surface diffusion model (CPHSDM) was used to predict the toluene breakthrough curve of continuous flow-packed columns containing LCF-Fe, and its capacity was 412 mg/g. Our study, which included material characterization, adsorption isotherms, kinetics, the impact of humidity and fixed bed performance modeling, demonstrated the suitability of lignin-based carbon fiber for volatile organic compound removal from gas streams.

关键词： lignin     carbon fiber     electrospinning     toluene     humidity    

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Shear behavior of ultra-high-performance concrete beams prestressed with external carbon fiber-reinforced

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1426-1440 doi: 10.1007/s11709-021-0783-z

摘要： The ultra-high-performance concrete (UHPC) and fiber-reinforced polymer (FRP) are well-accepted high-performance materials in the field of civil engineering. The combination of these advanced materials could contribute to improvement of structural performance and corrosion resistance. Unfortunately, only limited studies are available for shear behavior of UHPC beams reinforced with FRP bars, and few suggestions exist for prediction methods for shear capacity. This paper presents an experimental investigation on the shear behavior of UHPC beams reinforced with glass FRP (GFRP) and prestressed with external carbon FRP (CFRP) tendons. The failure mode of all specimens with various shear span to depth ratios from 1.7 to 4.5 was diagonal tension failure. The shear span to depth ratio had a significant influence on the shear capacity, and the effective prestressing stress affected the crack propagation. The experimental results were then applied to evaluate the equations given in different codes/recommendations for FRP-reinforced concrete structures or UHPC structures. The comparison results indicate that NF P 18-710 and JSCE CES82 could appropriately estimate shear capacity of the slender specimens with a shear span to depth ratio of 4.5. Further, a new shear design equation was proposed to take into account the effect of the shear span to depth ratio and the steel fiber content on shear capacity.

关键词： beam     external prestressing     ultra-high-performance concrete     fiber-reinforced polymers     shear behavior     design equation    

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Carbon performance evaluation model from the perspective of circular economy—The case of Chinese thermal

Zhifang ZHOU, Jinhao LIU, Huixiang ZENG, Mengmeng XU, Shihui LI

《工程管理前沿（英文）》 2022年 第9卷 第2期   页码 297-311 doi: 10.1007/s42524-020-0143-z

摘要： Carbon emission reduction is the only way to alleviate environmental problems, such as global warming. Effective evaluation of carbon performance can help enterprises to carry out energy saving and emission reduction activities to a certain extent and promote sustainable development. This paper constructs a carbon performance evaluation index system that includes the four dimensions of carbon resource (energy) input, cycle, output, and carbon management by incorporating the principles of circular economy and the theory of resource value circulation from the perspective of the flow trajectory of carbon-containing resources in the circulation of enterprises combined with the production characteristics of thermoelectric enterprises. Subsequently, combined with the case study, this paper discusses the scientific and practical nature of the system and provides another way of thinking for carbon performance evaluation of micro-enterprises in other industries. This paper expands the application boundary of matter–element model and supplements the literature of carbon performance, which has certain theoretical and practical significance.

关键词： circular economy     carbon performance     comprehensive evaluation     thermal power enterprise    

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Effect of different carbon sources on performance of an A

Dongliang Du, Chuanyi Zhang, Kuixia Zhao, Guangrong Sun, Siqi Zou, Limei Yuan, Shilong He

《环境科学与工程前沿（英文）》 2018年 第12卷 第2期 doi: 10.1007/s11783-017-0981-z

摘要： Effect of different carbon sources on purification performance and change of microbial community structure in a novel A N-MBR process were investigated. The results showed that when fed with acetate, propionate or acetate and propionate mixed (1:1) as carbon sources, the effluent COD, NH -N, TN and TP were lower than 30, 5, 15 and 0.5 mg·L , respectively. However, taken glucose as carbon source, the TP concentration of effluent reached 2.6 mg·L . Process analysis found that the amount of anaerobic phosphorus release would be the key factor to determine the above effectiveness. The acetate was beneficial to the growth of associated with biological phosphorus removal, which was the main cause of high efficiency phosphorus removal in this system. In addition, it could eliminate the associated with glycogen-accumulating organisms and guarantee high efficiency phosphorus uptake of phosphorus accumulating organisms in the system with acetate as carbon source.

关键词： Denitrifying phosphorus removal     Alternate anaerobic/anoxic-aerobic MBR (A2N-MBR)     Carbon source     Operation characteristic     Community structure    

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Ni/MgO catalyst prepared via dielectric-barrier discharge plasma with improved catalytic performancefor carbon dioxide reforming of methane

Yan LI,Zhehao WEI,Yong WANG

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 133-140 doi: 10.1007/s11705-014-1422-1

摘要： A Ni/MgO catalyst was prepared via novel dielectric-barrier discharge (DBD) plasma decomposition method. The combined characterization of Brunauer-Emmett-Teller measurement, X-ray diffraction, hydrogen temperature-programmed reduction and transmission electron microscopy shows that DBD plasma treatment enhances the support-metal interaction of Ni/MgO catalyst and facilitates the formation of smaller Ni particles. Sphere-like Ni particles form on plasma treated Ni/MgO catalysts. The plasma treated Ni/MgO catalyst shows a significantly improved low temperature activity and good stability for CO reforming of methane to syngas.

关键词： CO2 reforming     methane     dielectric-barrier discharge (DBD)     plasma     Ni/MgO    

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Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-based

《化学科学与工程前沿（英文）》 2022年 第16卷 第10期   页码 1460-1475 doi: 10.1007/s11705-022-2159-x

摘要： Carbon nanotubes-based materials have been identified as promising sorbents for efficient CO2 capture in fluidized beds, suffering from insufficient contact with CO2 for the high-level CO2 capture capacity. This study focuses on promoting the fluidizability of hard-to-fluidize pure and synthesized silica-coated amine-functionalized carbon nanotubes. The novel synthesized sorbent presents a superior sorption capacity of about 25 times higher than pure carbon nanotubes during 5 consecutive adsorption/regeneration cycles. The low-cost fluidizable-SiO2 nanoparticles are used as assistant material to improve the fluidity of carbon nanotubes-based sorbents. Results reveal that a minimum amount of 7.5 and 5 wt% SiO2 nanoparticles are required to achieve an agglomerate particulate fluidization behavior for pure and synthesized carbon nanotubes, respectively. Pure carbon nanotubes + 7.5 wt% SiO2 and synthesized carbon nanotubes + 5 wt% SiO2 indicates an agglomerate particulate fluidization characteristic, including the high-level bed expansion ratio, low minimum fluidization velocity (1.5 and 1.6 cm·s–1), high Richardson−Zakin index (5.2 and 5.3 > 5), and low Π value (83.2 and 84.8 < 100, respectively). Chemical modification of carbon nanotubes causes not only enhanced CO 2 uptake capacity but also decreases the required amount of silica additive to reach a homogeneous fluidization behavior for synthesized carbon nanotubes sorbent.

关键词： CO2 capture     CNT-based sorbents     fluidization     SiO2 nanoparticles     fluidized bed reactors    

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标题 作者 时间 类型 操作

Influence of pore structure on biologically activated carbon performance and biofilm microbial characteristics

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO

Zeinab JAMALZADEH, Mohammad HAGHIGHI, Nazli ASGARI

期刊论文

Tripotassium citrate monohydrate derived carbon nanosheets as a competent assistant to manganese dioxidewith remarkable performance in the supercapacitor

期刊论文

Insights into carbon-based materials for catalytic dehydrogenation of low-carbon alkanes and ethylbenzene

期刊论文

Construction of NiCoO nanoflake arrays on cellulose-derived carbon nanofibers as a freestanding electrodefor high-performance supercapacitors

期刊论文

“Charging” the cigarette butt: heteroatomic porous carbon nanosheets with edge-induced topological defectsfor enhanced oxygen evolution performance

期刊论文

Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodesfor high-performance supercapacitors

期刊论文

Recovery and reuse of floc sludge for high-performance capacitors

期刊论文

The preparation and performance of lignin-based activated carbon fiber adsorbents for treating gaseous

Min Song, Wei Zhang, Yongsheng Chen, Jinming Luo, John C. Crittenden

期刊论文

Shear behavior of ultra-high-performance concrete beams prestressed with external carbon fiber-reinforced

期刊论文

Carbon performance evaluation model from the perspective of circular economy—The case of Chinese thermal

Zhifang ZHOU, Jinhao LIU, Huixiang ZENG, Mengmeng XU, Shihui LI

期刊论文

Effect of different carbon sources on performance of an A

Dongliang Du, Chuanyi Zhang, Kuixia Zhao, Guangrong Sun, Siqi Zou, Limei Yuan, Shilong He

期刊论文

Ni/MgO catalyst prepared via dielectric-barrier discharge plasma with improved catalytic performancefor carbon dioxide reforming of methane

Yan LI,Zhehao WEI,Yong WANG

期刊论文

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-based

期刊论文